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Optic and structural study of new Co2+-Ln3+ hybrid coordination compounds with luminescent properties and their possible application in LED technology.

2nd International Conference on Optics and Laser technology

October 22, 2025 | Virtual Event

Adrian Olvera Nolasco

National Autonomous University of Mexico, Mexico

Abstract :

Currently, lanthanide ion coordination compounds are used in lighting technology, screens, money safety marks, and light phosphor converters. They present photoluminescent prop­erties, with fine emission bands unaffected by their chemical environment. [1-3] Lanthanide ion´s emissions can be improved by coordinating them to a chromophore that absorbs en­ergy and transfers it to the ion, thus enhancing luminescence. This ligand acts as a sensitiz­er (antenna effect).[4] Previous reports indicate that Salphen derivatives and their d-block metal coordination compounds may enhance lanthanides’ emissions. However, only Schiff-base coordination compounds with closed-shell d-block metals such as Zn2+ and Cd2+ have been used. [5-10] Coordination compounds containing ion metals like Cr3+ and Co2+ are dark materials due to charge transfer bands absorptions that may quench luminescence. We ob­served that salphen d-f (Co2+-Ln3+) hybrid coordination compounds display luminescence in solution or a solid dispersion. The thermal stability of the compounds above 200 °C and their photoluminescent properties could make them suitable for light phosphor conversion on LED technology.

Biography :

Adrian Olvera Nolasco obtained his B. Sc. (Chemistry) in 2018 and completed the M. Sc. (Chemistry) in 2021. He is pursuing a PhD in Chemistry at the Universidad Nacional Autónoma de México.