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Unravelling the dual photocatalytic behavior of highly luminescent auin nanoclusters for degradation of 4-Nitrophenol and Dye Pollutants

2nd Global Event on Materials Science and Engineering & 2nd World Congress on Nanotechnology

November 06-07-2025 | HYBRID EVENT

Amit Bharti

Panjab University, India

Abstract :

Bimetallic fluorescent nanomaterials have garnered significant attention owing to their su­perior photoluminescent and catalytic activities. Herein, a novel glutathione stabilized bi­metallic AuIn nanoclusters framework were synthesized for the first time via a rapid one-pot microwave-assisted approach, with complete formation achieved within 2 minutes, along with monometallic Au nanoclusters (AuNCs) for comparison. The comprehensive characteri­zation using UV-Vis and Fluorescence spectroscopy, HRTEM, DLS, XPS, FT-IR, EDX with map­ping, TGA, and zeta potential analysis which confirmed the formation of uniformly spherical AuIn nanoclusters framework with an average diameter of 125 nm and improved colloidal and thermal stability compared to only AuNCs. The photoluminescence studies revealed sig­nificantly enhanced emission for AuIn nanoclusters framework relative to AuNCs. Further, the photocatalytic behavior of novel AuIn nanoclusters framework was evaluated based on two applications, the reduction of 4-nitrophenol and degradation of toxic dyes, including both cationic and anionic dyes such as RhB, MB, MO, CR and RB. The AuIn nanoclusters catalyzed the 4-NP reduction within 60 seconds which is comparatively faster than AuNCs and exhibited superior dye degradation efficiency. The kinetic study confirmed that both processes pseudo first order kinetics. The fluorescent AuIn bimetallic nanoclusters framework demonstrated en­hanced photophysical and catalytic activity relative to monometallic AuNCs, demonstrating their potential as emerging platforms for advanced functional nanomaterials in future tech­nological applications.

Biography :

Amit Bharti is a research scholar (Ph.D.) in the Department of Chemistry at Panjab University. His research focuses on the design and synthesis of advanced fluorescent metallic and carbon-based nanomaterials with potential applications in catalysis, sensing, and the biomedical field. He also works on the self-assembly of or­ganic and biomolecules and has contributed as a co-author to published research in this area. His objective is to develop novel functional nanomaterials by integrating nanotechnology and supramolecular chemistry, with the goal of advancing the understanding and practical application of nanoscale materials to address complex environmental and technological challenges.